Title

Pincer-Supported Carbonyl Complexes of Cobalt(I)

Document Type

Article

Publication Date

2017

Publication Source

Organometallics

Volume

36

Issue

16

Inclusive pages

3104-3109

DOI

DOI: 10.1021/acs.organomet.7b00434

Peer Reviewed

yes

Abstract

A pair of POCOP-supported mono- and dicarbonyl complexes of Co have been prepared and crystallographically characterized. The reactivity of (tBuPOCOP)Co(CO) with H2, acids, and carbon monoxide has been compared to that of the previously reported Rh and Ir counterparts. Co is found to share reactivity traits with both Rh and Ir.

Disciplines

Chemistry

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