Title

The Novel Hydrogen-Rich Binuclear Cobalt Complex Anion, [(CoH3)2H3]5-

Document Type

Article

Publication Date

Winter 3-7-2014

Publication Source

Dalton Transactions

Volume

43

Issue

9

Inclusive pages

3412-3415

Publisher

Royal Society of Chemistry

Place of Publication

UK

Peer Reviewed

yes

Abstract

Hydrogen reacts with a mixture of cobalt bromide and phenylmagnesium bromide to yield a novel cobalt hydride species. EXAFS analysis reveals a binuclear cobalt hydride complex comprising three absorbers, principally a Co-Co centre, and also two types of supporting hydride ligands. Further, DFT, XANES, 1H NMR spectra and elemental analyses also support the title formulation.

Keywords

cobalt hydride, synthesis, hydrogen, EXAFS, XANES

Disciplines

Chemistry

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Link to Original Published Item

http://xlink.rsc.org/?doi=C3DT53117A