Document Type

Presentation

Document Subtype

Abstract

Presentation Date

6-9-2015

Conference Name

12th International Symposium on the Ordovician System

Conference Location

James Madison University, Harrisonburg, Virginia

Source of Publication

Stratigraphy

Publication Date

2015

Volume

12

Issue

2

Inclusive pages

98-99

Peer Review

No

Abstract

The Elgin Member of the Upper Ordovician (Katian) Maquoketa Formation of Iowa contains phosphorite beds consisting of millimeter-scale phosphatic fossils, primarily steinkerns. Similar beds occur in the coeval strata of the classic Cincinnatian Series around the Cincinnati, Ohio area. Initial sampling of the phosphate-rich beds of the Maquoketa allows comparison between the faunal composition and taphonomy of these beds and collections from the more extensively sampled Cincinnatian strata. We isolated these fossils by dissolution of bulk samples in acetic acid and examined the same strata in thin section to study the fossils in context. The Maquoketa diminutive phosphatized fossils have been interpreted as evidence of dwarfed faunas indicative of environmental stress, such as anoxia, which may have also contributed to phosphogenesis. An alternative explanation for the small size is that phosphogenesis was size-selective and that phosphatic particles were concentrated by reworking as less-durable shell material was destroyed. These hypotheses can be tested by examining the fauna for “normal” sized elements. Insoluble residue from sampled phosphate-rich strata in both field areas yields abundant molluscan steinkerns, as well as crinoid columnals, conodonts, scolecodonts, bryozoan zooecia steinkerns and other fossils associated with a normal marine fauna. In Cincinnatian occurrences, the composition of the phosphatic assemblages is variable but is a reflection of the variability of faunal composition seen in these strata rather than an indication of an unusual fauna associated with extreme conditions; most are associated with diverse marine assemblages. Insoluble residues from both areas yield steinkerns that precipitated in small pores within larger skeletons. This phenomenon can be seen in thin section, where phosphate is present within certain parts of the larger preserved skeletons. The maximum size of the steinkerns of the Maquoketa is larger than those of most Cincinnatian occurrences, although size is variable in Cincinnatian occurrences. In Cincinnatian strata the abundance of small phosphatic fossils correlates with evidence for reworking; heavily reworked beds yield the most residue. Examined in thin section, the sampled strata of the Maquoketa appear to be heavily reworked and represent an extreme endmember of this concentration of durable phosphatic material. Detailed examination using an SEM and associated XRF elemental mapping reveals that the phosphatic steinkerns of both localities are very similar in their taphonomy. Both consist of botryoidal growths of carbonate fluorapatite (CFA). The botryoidal growth appears to have nucleated on the walls of the original shell, first forming a lining of variable thickness. Some steinkerns have secondary botryoidal growths on the outside of the steinkern indicating continued precipitation of CFA after destruction of the original shell. This secondary precipitation suggests that reworking played a role not only in concentrating the phosphatic material but also in encouraging continued precipitation of CFA. The size of the available pore space appears to have played a role in encouraging the precipitation of CFA. In thin section the CFA is limited to smaller parts of larger shells, such as the apices of gastropods and did not precipitate on the inside of the larger, more open spaces within the shell. Many of the phosphate-filled spaces are also sediment-filled, suggesting that subdivision of the larger space into smaller pores enhanced the precipitation of CFA. The difference in the maximum size of the steinkern achieved in the different assemblages suggests that geochemical factors affected size limits. The most distinctive aspect of phosphate-rich Ordovician strata of mid-Laurentia is the degree of reworking that concentrated the durable small fossils. Details of taphonomy also suggest that phosphate precipitation was an iterative process enhanced by reworking, and that small pore spaces enhanced this mineralization, thus selectively preserving certain sizes and parts of the larger fauna.

Disciplines

Earth Sciences | Geochemistry | Paleobiology | Paleontology | Sedimentology

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