The Novel Hydrogen-Rich Binuclear Cobalt Complex Anion, [(CoH3)2H3]5-
Royal Society of Chemistry
Place of Publication
Hydrogen reacts with a mixture of cobalt bromide and phenylmagnesium bromide to yield a novel cobalt hydride species. EXAFS analysis reveals a binuclear cobalt hydride complex comprising three absorbers, principally a Co-Co centre, and also two types of supporting hydride ligands. Further, DFT, XANES, 1H NMR spectra and elemental analyses also support the title formulation.
cobalt hydride, synthesis, hydrogen, EXAFS, XANES
Donald Edward Linn Jr, Jerod Kieser, and Jason Shearer (2014).
The Novel Hydrogen-Rich Binuclear Cobalt Complex Anion, [(CoH3)2H3]5-. Dalton Transactions.43 (9), 3412-3415. UK: Royal Society of Chemistry.